The roof must be thoroughly cleaned, and allowed to dry thoroughly. This is a critical step to ensure a successful coating application. Be careful not to damage the lap seams. Care should be taken when pressure washing not to disturb the integrity of the underlying roof membrane particularly where there are adhered seams. Refer to the specific coating manufacturer you are using for their specific requirements for roof preparation.
Jennifer, I'm not an expert on the health effects of closed cell foam. A lot of people live in houses with closed cell foam and have no health problems from it, at least not short-term, acute problems. I do know of one person who had it removed from her crawl space because she was convinced it caused her dog to get sick, but I know only what she told me.  
R-value is the term given to thermal resistance to heat flow. The higher the R-value of an insulation product, the more effective the insulation properties. Spray polyurethane foam comes in a range of densities and cel structure. Low density foams are referred to as Open Cel SPF while higher density foams are referred to as Closed Cel foam. 1.8-2 pound polyurethane foam has the highest R-value of readily available spray foam insulation used in homes and buildings.[4] 

Roof Spray Foam Insulation

The product is an acrylic coating, which is packed conveniently for ease of use. As it is also in one-gallon size, you can rely on its supreme area coverage reaching up to 125 square feet. The Dicor rubber roof coating is also very easy to apply. When shopping around for a roof coating, we believe it pays off to find an easy to apply product for fast results. It is one of the best qualities of the RV roof coating that makes it a top pick in the category.

This is in great contrast to my friend's experience. Her attic spaces were sprayed and the foam is actually pretty, and I was in her attic 6-7 days after it was sprayed and could hardly smell anything when I stuck my face up to the foam. And she did not have to clean up one speck of dust during or after the spraying. I got the name/number of the guy from her who managed her attic project, but between the time he did my house and the time he did her house, he was let go from the company who did her attic and hired by another company. He assured me everything would be the same, etc., etc., and I had no reason to believe anything had changed, but the sprayers who did my house later admitted they had never sprayed an attic before and I also found out that the foam used in my attic was from a different manufacturer. Neither my friend nor I had any idea this guy was with different company then, until the week after they filled my attic with off ratio foam, and my home with toxic vapors.  
Roof coatings can add 25 years to the service life of a roof and reduce the amount of discarded roofing materials that end up in landfills. The infrared image on the right shows 175 °F (79 °C) on the uncoated (black) section of the modified bitumen roof. The coated (white) section is 79 °F (26 °C). Field studies have shown that cool roof coatings can lower rooftop temperatures and reduce air conditioning bills.

Roof Coating