Fill and seal expanding foam sealant is urethane Fill and seal expanding foam sealant is urethane foam designed to fill large areas quickly and permanently. Uses include filling holes cracks or gaps that require a complete airtight and waterproof seal but are too large to be filled with ordinary caulk. The foam expands approximately 3 times its original ...  More + Product Details Close
The roof must be thoroughly cleaned, and allowed to dry thoroughly. This is a critical step to ensure a successful coating application. Be careful not to damage the lap seams. Care should be taken when pressure washing not to disturb the integrity of the underlying roof membrane particularly where there are adhered seams. Refer to the specific coating manufacturer you are using for their specific requirements for roof preparation.
What do you mean by "our AC units require fresh air ventilation"? Fresh air doesn't come from the attic. If there's an atmospheric combustion appliance in the attic, such as an 80 AFUE furnace, then you shouldn't be encapsulating the attic anyway. If that's the case, you don't want spray foam on the roofline at all. You can either change out the furnace to a sealed combustion unit or do your insulating and air-sealing at the flat-ceiling level.
I have used the Froth-Pak 200 to air-seal rim joists--the area above the foundation wall in a basement. The first time I used it I did not shake the canisters well enough and the foam did not cure properly. Don't just shake the box for a few seconds. I take the tanks out of the box so I can shake/invert each tank for a minute or two. You will be able to hear the chemical sloshing around in the tanks. Also, don't ignore the recommended temperature for application--around 75 degrees F.
The United States has adapted to using sprayfoam insulation and a new technology called Wall Injection to retrofit existing wall construction by drilling small holes between wall studs in the structures framing and filling the void with a less aggressive expanding water based foam. This allows existing home and business owners to conserve energy by creating a thermal envelope in their existing structure.

Roof Coating Seal