I've seen this only once, and it was with closed cell foam, but I've heard of it happening with open cell foam, too. I don't know the details, but I've heard it could result from a bad batch of chemicals, improper mixing, or too high a temperature. Whatever the cause, it's not a good thing. The photo below shows how the spray foam pulled away from the studs. A little bit of uninsulated area like that adds up to a lot of heat loss/gain when the whole house has that problem, as it did here.
The Gardner 4.75 Gallon Heavy Duty Foundation Coating The Gardner 4.75 Gallon Heavy Duty Foundation Coating is ideal for sealing concrete block and poured foundations fence and deck posts retaining walls and metal surfaces. Its high penetrating seal resists damage and deterioration due to moisture and insects. When applied properly this solvent-based asphalt coating helps prolong the life ...  More + Product Details Close
In general, cantilevered steel beams are a nightmare. If part of the steel beam is in contact with exterior temperatures, then it's best if the interior portion of the steel beam is covered on all sides with insulation. This is generally impossible (because the interior portion of the cantilevered beam generally supports a load, meaning that you can't wrap the steel beam in insulation on all sides). http://youtu.be/ggLAUsiuI_o
Fill and seal expanding foam sealant is urethane Fill and seal expanding foam sealant is urethane foam designed to fill large areas quickly and permanently. Uses include filling holes cracks or gaps that require a complete airtight and waterproof seal but are too large to be filled with ordinary caulk. The foam expands approximately 3 times its original ...  More + Product Details Close

How Much Is Spray Foam Insulation Installation

RE: my June 12 post...We went ahead and had the attic sprayed with a Soy-based product. Stayed in a hotel for 3 nites. Still smelled a little bad but that's gone away over time. I'm very glad we didn't use the other foam as even that much outgassing of a petrochemical could have sent my wife to the hospital. Unfortunately, the spray crew didn't speak English(at least not to me) and were kinda lazy, so they ended up spraying over some can fixtures from the kitchen below that were not insulation-contact rated. So I hired an electrician to come out, pull down the cans, pull out what he thought was an appropriate amount of foam to create a big enough air space and then re-install the cans. I billed the firm for the electrician plus an extra night we had to stay in the hotel and they paid, no questions asked. Guess they knew they had screwed up.  
These coatings are emulsified asphalt and consist of asphalt particles dispersed in water; they utilize clay as the emulsifying component. These coatings also contain many types of organic and/or inorganic fibers and fillers to provide extra strength to the coating. These coatings are available in black, brown, or as a reflective coating when titanium dioxide or aluminum pigments are added. https://www.youtube.com/watch?v=ggLAUsiuI_o&hc_location=ufi
Warning: EnergyGuard™ Elastomeric Roof Coatings can freeze below 32° F. This is because the product is water based. In case of freezing temperatures, stop the application process. After application, you must allow the product time to dry before exposing the elastomeric roof coating to foot traffic or water. You should also cover the containers and dispose them responsibly after application. In case you or someone else i.e. a child ingests the coating seek immediate medical attention. Don't induce vomiting.
The United States has adapted to using sprayfoam insulation and a new technology called Wall Injection to retrofit existing wall construction by drilling small holes between wall studs in the structures framing and filling the void with a less aggressive expanding water based foam. This allows existing home and business owners to conserve energy by creating a thermal envelope in their existing structure.

Roof Coating Seal